79618-45-4

Upstream product

• 1521-51-3 rac-3-bromocyclohexene 
• 21331-58-8 ethyl (cyclohexen-3-yl)acetate 
• 16452-34-9 2-(cyclohex-2-enyl)ethanol 

Downstream Products

• 42185-50-2 Methyl-2(cyclohexen-2yl)-5pentanon-3 
• 91954-29-9 1-<5-Methyl-hexen-(4)-yl-(1)>-cyclohexen-(2) 
• 137346-57-7 2-(cyclohex-2-enyl)ethanesulphinic acid sodium salt 
• 1231177-40-4 (4-chloro-phenyl)-{3-[1-phenyl sulfanyl-(E)-methylidene]-3,4,4a, 5,6,8a-hexahydro-thiochromene-(2Z)-ylidene}-amine 
• 1231177-58-4 (4-chlorophenyl)-(3,4,4a, 5,6,8a-hexahydro-thiochromene-2-ylidene)-amine 
• 1231177-60-8 2-(4-chloro-phenylamino)-4a,5,6,8a-tetrahydro-4H-thiochromene-3-carbaldehyde 
• 1231177-56-2 N-(4-chlorophenyl)-3-(2-cyclohexene-1-yl)thiopropionamide 
• 79618-46-5 5-(2-cyclohexen-1-yl)-(E)-2-penten-1-ol 
• 79618-55-6 5-(2-cyclohexen-1-yl)-2-pentyn-1-ol 
• 137346-58-8 cyclohexenylethanesulphinic acid 
• 133216-87-2 2-(cyclohex-2-en-1-yl)ethane-1-sulfonyl chloride 
• 42185-49-9 (Cyclohexen-2yl)-4butanon-2 

Relevant academic research and scientific papers

Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C-H Amination

Both arylsulfonyl and alkylsulfonyl azides can be effectively activated by the cobalt(II) complexes of D2-symmetric chiral amidoporphyrins for enantioselective radical 1,5-C-H amination to stereoselectively construct 5-membered cyclic sulfonami

Sulphonate Esters as Sources of Sulphonyl Radicals; Ring-closure Reactions of Alk-4- and -5-enesulphonyl Radicals

Alkyl alkanesulphonates and arenesulphonates were found to be useful sources of sulphonyl radicals, particularly for spectroscopic work, when treated with organotin or organosilyl radicals.Allyl, propynyl and penta-2,4-dienyl methanesulphonates gave, however, allyl, propynyl and pentadienyl radicals, respectively.Sulphonyl radicals generated in this way added efficiently to alk-1-enes with electron-releasing substituents, and the EPR spectra of the adduct radicals were recorded.A variety of radical initiation systems were tried on pent-4-enesulphonyl chloride.The pent-4-enesulphonyl radical cyclised mainly in the endo mode to give the six-membered-ring sulphone.Similarly, the hex-5-enesulphonyl radical cyclised to give thiepane 1,1-dioxide, with a seven-membered ring.The cyclohex-2-enylethanesulphonyl radical cyclised mainly in the exo mode to give 2-chloro-9-thiabicyclononane 9,9-dioxide.The mechanisms of these reactions are discussed.

Copper(I) Catalysis of Olefin Photoreactions. 10. Synthesis of Multicyclic Carbon Networks by Photobicyclization

The synthetic utility of copper-catalyzed photobicyclization for construction of tricyclic ring systems is explored.UV irradiation of several monocyclic β- and γ-(4-pentenyl)allyl alcohols in the presence of copper(I) trifluoromethanesulfonate (CuOTf) gen