16452-34-9

Basic information

• Product Name: 2-Cyclohexene-1-ethanol
• Synonyms: 2-(cyclohex-2-enyl)ethanol;(2-cyclohexen-1-yl) 1-ethanol;2-(3-Cyclohexenyl)ethanol;2-(1-cyclohex-2-enyl)-ethanol;3-(2-hydroxyethyl)-1-cyclohexene;2-Cyclohexene-1-ethanol;2-(2-cyclohexen-1-yl)ethanol
• CAS NO: 16452-34-9
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• Mol File: 16452-34-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-ethanol(16452-34-9)
• EPA Substance Registry System: 2-Cyclohexene-1-ethanol(16452-34-9)

Safety Data

• Hazardous Substances Data: 16452-34-9(Hazardous Substances Data)

Upstream product

• 75-21-8 oxirane 
• 110-83-8 cyclohexene 
• 21331-58-8 ethyl (cyclohexen-3-yl)acetate 
• 50-00-0 formaldehyd 
• 34825-93-9 1-bromomethylcyclohex-2-ene 
• 19509-49-0 3-chloromethylcyclohexene 
• 80816-25-7 2-cyclohexenyl vinyl ether 
• 40098-43-9 diisobutyl[(1E)-oct-1-en-1-yl]aluminum 
• 112052-21-8 methyl 2-(cyclohex-2-en-1-yl)acetate 
• 3675-31-8 2-(cyclohex-2-enyl)acetic acid 
• 34939-28-1 dimethyl 2-(cyclohex-2-en-1-yl)malonate 
• 76644-52-5 rac-3-acetoxycyclohexene 
• 103668-33-3 3-hydroxymethylcyclohexene 
• 1091604-72-6 C₁₃H₂₆OSi 

Downstream Products

• 79618-45-4 3-(2-bromoethyl)cyclohex-1-ene 
• 672903-58-1 2-(2-cyclohexenyl)ethyl methanesulfonate 
• 16423-30-6 2-(Δ²-Cyclohexenyl)-ethyl-p-brom-benzolsulfonat 
• 697249-17-5 1-[2-(2-cyclohexen-1-yl)ethyl]-3-methoxy-1H-pyrrole-2,5-dione 
• 19509-51-4 3-(β-chloroethyl)cyclohexene 
• 19656-95-2 2-cyclohexenylacetaldehyde 
• 1379450-03-9 3-(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)cyclohex-2-en-1-one 
• 42185-50-2 Methyl-2(cyclohexen-2yl)-5pentanon-3 
• 42185-49-9 (Cyclohexen-2yl)-4butanon-2 
• 82725-89-1 3-(2-Cyclohexenyl)propannitrile 
• 76837-82-6 (+/-)-3-(cyclohex-2-enyl)propanoic acid 
• 15745-87-6 3-cyclohex-2-en-1-ylpropan-1-ol 
• 79618-54-5 5-(2-cyclohexen-1-yl)-1-(α-ethoxyethoxy)-2-pentyne 

Relevant articles and documents

Pyrrolidines and Piperidines by Ligand-Enabled Aza-Heck Cyclizations and Cascades of N-(Pentafluorobenzoyloxy)carbamates

Ligand-enabled aza-Heck cyclizations and cascades of N-(pentafluorobenzoyloxy)carbamates are described. These studies encompass the first examples of efficient non-biased 6-exo aza-Heck cyclizations. The methodology provides direct and flexible access to carbamate protected pyrrolidines and piperidines.

Low-valent titanium-mediated stereoselective alkylation of allylic alcohols

We have developed low-valent titanium-mediated 1,3-transpositive cross-coupling reactions of acyclic and cyclic allylic alcohols for the stereoselective introduction of ethyl, 2-silylethyl, 2-phenethyl, and alkenyl groups. Cross-coupling of an allylic alcohol with a vinylsilane or styrene derivative is particularly noteworthy, as an efficient cross-selective coupling of two alkenes has been elusive. The stereochemistry of the cross-coupling alkylation is consistent with syn addition/β-elimination.