79635-97-5

Upstream product

• 92516-59-1 methyl 6-azido-2,3,4-tri-O-benzoyl-6-deoxy-α-D-idopyranoside 
• 13566-32-0 (4aR,6S,7S,8S,8aR)-6-methoxy-2-phenylhexahydropyrano[3,2-d][1,3]dioxine-7,8-diol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 92516-59-1 methyl 6-azido-2,3,4-tri-O-benzoyl-6-deoxy-α-D-idopyranoside 

Relevant academic research and scientific papers

Dioxolanylium Ions Derived from Carbohydrates. IX. Rearrangement between Dioxolanylium and Dioxanylium Ions

The formation of 4,6-acetoxonium and benzoxonium ion derivatives of methyl gluco-, manno-, galacto- and idopyranosides from the 6-azido-6-deoxy compounds on treatment with nitrosonium ion is described and the formation and rearrangement of the 3,5-benzoxonium ion derived from methyl α-d-xylofuranoside discussed.

Dioxolanylium Ions Derived from Carbohydrates. VII. Rearrangements between Derivatives of Methyl α-D-Manno-, Altro- and Idopyranosides and Their Reaction with Nucleophiles

Reaction of derivatives of methyl 2,3-O-benzylidene-α-D-mannopyranoside or 3,4-O-benzylidene-α-D-altropyranoside with trityl fluoroborate gave the same equilibrium mixture of benzoxonium ions (4->//-6) of the manno, altro and ido configuration.Throu