79643-72-4

Basic information

• Product Name: t-2-hydroxy-1-trimethylsilylcyclohexan-r-1-yl thiocyanate
• CAS NO: 79643-72-4
• Molecular Weight: 229.418
• Mol File: 79643-72-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-2-hydroxy-1-trimethylsilylcyclohexan-r-1-yl thiocyanate(CAS DataBase Reference)
• NIST Chemistry Reference: t-2-hydroxy-1-trimethylsilylcyclohexan-r-1-yl thiocyanate(79643-72-4)
• EPA Substance Registry System: t-2-hydroxy-1-trimethylsilylcyclohexan-r-1-yl thiocyanate(79643-72-4)

Safety Data

• Hazardous Substances Data: 79643-72-4(Hazardous Substances Data)

Upstream product

• 60484-85-7 1-trimethylsilyl-7-oxabicyclo<4.1.0>heptane 
• 463-56-9 thiocyanic acid 

Downstream Products

• 79643-74-6 t-2-methylsulphonyloxy-1-trimethylsilylcyclohexan-r-1-yl thiocyanate 
• 79643-75-7 t-2-mercapto-2-trimethylsilylcyclohexan-r-1-ol 

Relevant articles and documents

Some Epoxide Ring-opening Reactions of αβ-Epoxysilanes

Epoxide ring-opening of 1,2-epoxy-1-trimethylsilylcyclohexane (3) has given a range of the 2-substituted 2-trimethylsilylcyclohexanols (4; X = H, OH, OMe, OCH2CH=CH2, Br, I, SCN) in which attack by nucleophile has occured at the carbon α to silicon.The products (4) have been transformed into a number of functionalised silanes, including the silyl-episulphide (9).Other epoxides which have been less extensively studied are the conformationally biased epoxysilanes (10) and (11), the eight-membered ring epoxysilanes (17) and (21) and the two stereoisomeric 2,3-epoxy-3-trimethylsilylpentanes (26) and (29).Epoxide ring-opening adducts were obtained after treatment with H+-MeOH in all cases except for compound (17), where the bicyclic alcohol (18) was formed by a transannular reaction.