79646-57-4Relevant academic research and scientific papers
ORIENTATION SELECTIVE BOND CLEAVAGE REACTIONS OF BIPHENYL-FUSED 1,2-DIPHENYLCYCLOBUTANES INITIATED BY ELECTRON TRANSFER1
Yamashita, Yoshiro,Yaegashi, Hisao,Mukai, Toshio
, p. 3579 - 3582 (1985)
Biphenyl-fused 1,2-diphenylcyclobutanes underwent orientation selective bond cleavage in the photosensitized reactions using DCA as a sensitizer or aminium cation radical catalyzed reactions.
Photochemistry of the Phenanthrene-Stilbene System. Cycloaddition and Singlet-Sensitized Isomerization
Caldwell, Richard A.,Mizuno, Kazuhiko,Hansen, P. E.,Vo, L. P.,Frentrup, M.,Ho, C. D.
, p. 7263 - 7269 (2007/10/02)
Photocycloaddition of phenanthrenes to stilbenes is a general and remarkably facile reaction.Two isomeric trans adducts often result with unsymmetrical phenanthrenes.The product with cis-stilbene and 9-cyanophenanthrene is the crowded cis,endo isomer.With 9-cyanophenanthrene and trans-stilbene, geometric isomerization occurs but only in a triplet process.With cis-stilbene, geometric isomerization results from the triplet, and both geometric and valence isomerizations can be induced by singlet 9-cyanophenanthrene.The reactivity of the stilbene isomers can be accounted for by an algorithm we have previously derived, as can the 20- to 30-fold enhancement of stylbenes over styrenes as a reactant in cycloaddition to phenanthrene.The possibility of singlet-sensitized valence isomerization as a mechanism for storage of solar energy is discussed.
