796843-82-8

Basic information

• Product Name: (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane
• Synonyms: (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane
• CAS NO: 796843-82-8
• Molecular Weight: 530.907
• Mol File: 796843-82-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane(796843-82-8)
• EPA Substance Registry System: (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane(796843-82-8)

Safety Data

• Hazardous Substances Data: 796843-82-8(Hazardous Substances Data)

Upstream product

• 639071-46-8 (2S)-2-[(1S)-1-(4-methoxyphenoxy)prop-2-en-1-yl]oxirane 
• 220433-62-5 (+/-)-8-(tert-butyldimethylsilyloxy)oct-1-en-3-ol 
• 25047-67-0 n-heptyllithium 
• 796844-04-7 1-({(1S)-1-[(1S)-1-(benzyloxy)nonyl]prop-2-en-1-yl}oxy)-4-methoxybenzene 
• 796843-78-2 (3S,4S)-3-3(4-methoxyphenoxy)dodec-1-en-4-ol 
• 796843-80-6 (3R)-8-{[(tert-butyl)(dimethyl)silyl]oxy}oct-1-en-3-ol 
• 796843-79-3 (3S,4S)-4-(benzyloxy)dodec-1-en-3-ol 
• 796843-81-7 tert-butyl(1R)-1-(5-{[tert-butyldimethylsilyl]oxy}pentyl)prop-2-en-1-yl carbonate 

Downstream Products

• 796843-83-9 5-{(2R,5S)-5-[(1S)-1-(benzyloxy)nonyl]tetrahydrofuran-2-yl}pentan-1-ol 

Relevant articles and documents

Stereodivergent construction of cyclic ethers by a regioselective and enantiospecific rhodium-catalyzed allylic etherification: Total synthesis of gaur acid

A dramatic enhancement of the stereospecificity of the title reaction was observed with trimethylphosphite-modified copper(I) alkoxide reagents. The combination of this reaction with ring-closing metathesis provides a direct approach to cis- and trans-dis