797050-35-2Relevant academic research and scientific papers
Stereoselective synthesis and structure of butalactin and lactone II isolated from Streptomyces species
Ueki, Toshihiko,Kinoshita, Takamasa
, p. 2777 - 2785 (2007/10/03)
The synthesis and stereostructure of butalactin and lactone II isolated from streptomyces species was analyzed. It was observed that butalactin exhibited moderate antibacterial activity against gram positive bacteria. It was also observed that stereoselectivity of the lactones was in the ratio 8:1. The results show that an interesting rearrangement is formed due to intramolecular double esterification of 3-oxymethyl anion.
Synthesis and absolute configuration of lactone II isolated from Streptomyces sp. Go 40/10
Ueki,Morimoto,Kinoshita
, p. 1820 - 1821 (2007/10/03)
All four possible stereoisomers of lactone II isolated from Streptomyces sp. Go 40/10, an autoregulator, have been efficiently synthesized in a stereoselective manner starting from (S)-malic acid and sorbic acid, and the absolute configuration was determined to be 2S, 3S, 9R, 10S.
