79732-89-1Relevant academic research and scientific papers
Asymmetric Induction during Organometallic Conjugate Addition to Enantiomerically Pure 2-(Arylsulfinyl)-2-cyclopentenones
Posner, Gary H.,Mallamo, John P.,Hulce, Martin,Frye, Leah L.
, p. 4180 - 4185 (2007/10/02)
Virtually complete asymmetric induction is achieved during methyl-, vinyl- and naphthylmetallic conjugate addition to enantiomerically pure (S)-(+)-2-(p-tolylsulfinyl)-2-cyclopentenone ((S)-(+)-1). (R)-3-Methylcyclopentanone is obtained when the enone sul
Complete Asymmetric Induction in Synthesis of Enantiomerically Pure Steroid Intermediates of Natural Configuration
Posner, Gary H.,Hulce, Martin,Mallamo, John P.,Drexler, Steven A.,Clardy, Jon
, p. 5244 - 5246 (2007/10/02)
Enantiomerically pure steroid intermediates (S)-1 and (S)-(+)-2 of natural absolute configuration have been prepared with complete asymmetric induction during zinc dibromide mediated vinylmagnesium bromide conjugate addition to enantiomerically pure, crys
