79759-08-3

Upstream product

• 32724-90-6 (4,5-dichloro-2-nitro-phenyl)-phenyl-amine 
• 5348-42-5 4,5-Dichloro-1,2-phenylenediamine 
• 108-86-1 bromobenzene 
• 62-53-3 aniline 
• 2339-78-8 1,2-dichloro-4-fluoro-5-nitrobenzene 

Downstream Products

• 151385-87-4 4,5-Dichloro-N-(3-methyl-butyl)-N'-phenyl-benzene-1,2-diamine 
• 151620-67-6 3-Amino-7,8-dichloro-1-(3-methyl-butyl)-5-phenyl-1,5-dihydro-benzo[b][1,4]diazepine-2,4-dione 
• 151385-88-5 7,8-Dichloro-1-(3-methyl-butyl)-5-phenyl-3-(phenyl-hydrazono)-1,5-dihydro-benzo[b][1,4]diazepine-2,4-dione 
• 79759-49-2 5,6-Dichloro-1-phenyl-1,3-dihydro-benzoimidazol-2-one 
• 79759-50-5 5,6-Dichloro-1-methyl-3-phenyl-1,3-dihydro-benzoimidazol-2-one 

Relevant academic research and scientific papers

Square planar nickel(II) complexes with halogenated o- diiminobenzosemiquinonato ligation: Synthesis, characterization, and redox property

Seven square planar bis(o-diiminobenzosemiquinonato)nickel(II) complexes, [Ni(o-C6H4(NH)(NAr))2] (Ar=Mes, 1; p-F-C 6H4, 2; p-Cl-C6H4, 3), [Ni(o-4,5-F2-C6H2(NH)(NPh))2] (4), and [Ni(o-4,5-Cl2-C6H2(NH)(NAr))2] (Ar=Ph, 5; 2,6-F2-C6H3, 6; 2,6-Cl 2-C6H3, 7), have been synthesized and characterized by 1H NMR, 13C NMR, 19F NMR, IR, UV-Vis-NIR, elemental analyses, HRMS, as well as single-crystal X-ray diffraction studies (1 and 7). The cyclic voltammograms of these complexes exhibit two reversible redox processes of [NiL2]0/1- and [NiL2]1-/2-, and one irreversible process of [NiL 2]0/2+. Substituent effects on the redox properties of these complexes, in addition with those of the known complexes [Ni(o-C 6H4(NH)(NPh))2] (8) and [Ni(o-3,5-Bu t2-C6H2(NH)2) 2] (9), are identified by comparing the half-wave potentials of the reduction waves, as 1≈92] parallels the electron-donating and -withdrawing ability of the substituent group. Reduction of 1 with one or two equivalents of sodium metal in THF has led to the isolation of [Na(THF) 3][1] and [Na(THF)3]2[1]. The structure data of these two complexes revealed by low-temperature X-ray crystallography suggest their corresponding electronic structures of [NiII(1L ·1-)(1L2-)]1- and [Ni II(1L2-)2]2-, which are in line with those of [9]n (n=1-, 2-) suggested by spectroelectrochemical study. Copyright

Novel 1,5-benzodiazepines as CCK-B ligands. Effect of aryl-carbamic substituents at the C-3 position together with halogen substitution on the benzo-fused ring

The synthesis and biological evaluation as potential CCK-B receptor ligands of a number of 1-isopentyl-3-aryloxycarbamoyl-5-aryl-1,5-benzodiazepines substituted with halogen atoms on the benzo-fused ring is here briefly discussed.