79769-67-8Relevant academic research and scientific papers
CONFORMATIONAL ANALYSIS IN THE SERIES OF 10-BENZYLANTHRONES
Shevchenko, S. M.,Yakobsons, Yu. K.,Gindin, V. A.,Gravitis, Ya. A.
, p. 158 - 166 (2007/10/02)
The stable conformations and the potential of internal rotation about the C10-CH2 bond in 10-benzyl-9(10H)-anthracenone (10-benzylanthrone) were calculated by the method of atom-atom potential functions with optimization of the geometry.The cal
Regioselective Alkylation of Anthrahydroquinone and Anthrone in Water with Quinonemethides and Other Alkylating Agents
Dimmel, Donald R.,Shepard, Donaline
, p. 22 - 29 (2007/10/02)
Antrahydroquinone (AHQ) and anthrone are alkylated in the C10 position by quinonemethides, generated in situ from p-acetoxybenzyl chlorides, to give adducts 13-15, 24, 25, 28, 29, and 32.Aqueous alkylations of AHQ with methyl vinyl ketone, cinnamaldehyde, and benzyl chloride also produces C10-substituted 10-hydroxyanthrones.Simple ketones and aldehydes do not, however, alkylate AHQ in aqueous alkali.
