58343-58-1

Basic information

• Product Name: 9,10-Anthracenediol, 9,10-dihydro-
• Synonyms: 9,10-Dihydro-9,10-dihydroxyanthracene;9,10-dihydroanthracen-9,10-ol;9,10-Anthracenediol,9,10-dihydro;9,10-Dihydroxy-9,10-dihydroanthracene;9,10-dihydro-anthracene-9,10-diol;9,10-dihydro-9,10-anthracenediol;9,10-dihydroxyanthracene
• CAS NO: 58343-58-1
• Molecular Formula: C14H12O2
• Molecular Weight: 212.248
• Mol File: 58343-58-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 9,10-Anthracenediol, 9,10-dihydro-(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-Anthracenediol, 9,10-dihydro-(58343-58-1)
• EPA Substance Registry System: 9,10-Anthracenediol, 9,10-dihydro-(58343-58-1)

Safety Data

• Hazardous Substances Data: 58343-58-1(Hazardous Substances Data)

Upstream product

• 120-12-7 anthracene 
• 613-31-0 9,10-dihydroanthracene 
• 614-45-9 tert-Butyl peroxybenzoate 
• 84-65-1 9,10-phenanthrenequinone 

Downstream Products

• 79769-67-8 10-hydroxy-10-(4-hydroxy-3-methoxyphenylmethyl)-9(10H)anthracenone 
• 6938-79-0 9,10-dihydro-9,10-dihydroxyanthracene diacetate 
• 82247-11-8 Acetic acid 3-(4-acetoxy-3-methoxy-phenyl)-3-(9-hydroxy-10-oxo-9,10-dihydro-anthracen-9-yl)-2-(2-methoxy-phenoxy)-propyl ester 
• 82247-21-0 1-(3-methoxy-4-acetoxyphenyl)-1-(10-acetoxy-9-oxoanthracen-10-yl)-2-(2-methoxyphenoxy)ethane 
• 82247-00-5 1-(3-methoxy-4-acetoxyphenyl)-1-(10-hydroxy-9-oxoanthracen-10-yl)-2-(2-methoxyphenoxy)ethane 
• 79769-69-0 10-acetoxy-10-(4-acetoxybenzyl)-9(10H)-anthracenone 
• 79769-68-9 10-hydroxy-10-(4-acetoxybenzyl)-9(10H)-anthracenone 
• 69544-83-8 4-hydroxy-10-benzylidene-10H-anthracen-9-one 
• 79769-75-8 10-hydroxy-10-(1-phenyl-3-oxopropyl)-9(10H)-anthracenone hemiacetal 
• 78787-97-0 10-hydroxy-10-benzyl-9(10H)-anthracenone 
• 84-65-1 9,10-phenanthrenequinone 
• 82247-10-7 threo-1-(3-methoxy-4-hydroxyphenyl)-1-(10-hydroxy-9-oxoanthracen-10-yl)-2-(2-methoxyphenoxy)-3-acetoxypropane 
• 79769-66-7 10-hydroxy-10-(3,5-dichloro-4-hydroxybenzyl)-9(10H)-anthracenone 
• 82247-12-9 C₃₅H₃₀⁽²⁾H₂O₉ 

Relevant articles and documents

Copper-catalyzed benzylic oxidation of C(sp3)-H bonds

A selective oxidation of benzylic C(sp3)-H bonds to C(sp 3)-O bonds catalyzed by copper complexes of quinoline-imine ligands was developed with peresters as oxidants under mild reaction conditions, which converted benzylic methylenes directly into benzylic alcohols and esters by means of direct C-H bond functionalization.

From surface-inspired oxovanadium silsesquioxane models to active catalysts for the oxidation of alcohols with O2-The cinnamic acid/ metavanadate system

Silsesquioxane dioxovanadate(V) complexes were investigated with respect to their potential as a catalyst for the oxidative dehydrogenation of alcohols with O2 as an oxidant. The turnover frequencies determined were comparatively low, but during the oxidation of cinnamic alcohol an increase in activity was observed in the course of the process, which was inspected more closely. It turned out that during the oxidation of cinnamic alcohol, not only was the aldehyde formed but also cinnamic acid, which in turn reacts with the silsesquioxane complex employed to give NBu4- [O2V(O 2CC2H2Ph)2], which can also be obtained from NBu4VO3 and cinnamic acid and represents a far more active catalyst, not only for cinnamic alcohol but also for other activated alcohols and hydrocarbons. The rate-determining step of the conversion corresponds to an hydrogen-atom abstraction from the C-H units, as shown by the determination of the kinetic isotope effect in case of 9-hydroxyfluorene, and the reoxidation of the reduced catalyst proceeds via a peroxo intermediate, which is also capable of oxidizing one alcohol equivalent. Furthermore the influence of the organic residues at the carboxylate ligands on the catalyst performance was investigated, which showed that the activity increases with decreasing pKs value. Moreover, it was found that during the oxidation the catalyst slowly decomposes, but can be regenerated by addition of excessive carboxylic acid.

Photochemistry of anthracene in water

Photolysis of anthracene (350 nm) in aerated water yields endoperoxide and 9,10-anthraquinone as the major primary photoproducts. Photolysis of anthracene in oxygen-deficient aqueous solutions yields the three isomers of 10,10'-dihydroxy-9,9',10,10'-tetrahydro-9,9'-bianthryl as the primary photoproduct. Involvement of a cation radical mechanism is suggested.