797762-54-0Relevant articles and documents
Synthetic stitching with silicon: Geminal alkylation-hydroxylation of alkynyl carbonyl compounds
Trost, Barry M.,Ball, Zachary T.
, p. 13942 - 13944 (2007/10/03)
A new strategy for the synthesis of β-carbonyl-substituted tertiary alcohols from α,β-alkynyl ketones and esters has been demonstrated. A silicon tether is used to internally deliver an alkyl group, which, combined with a C-Si to C-O transformation, can r