797789-08-3Relevant academic research and scientific papers
End-cap exchange of rotaxane by the Tsuji-Trost allylation reaction
Kihara, Nobuhiro,Motoda, Seiko,Yokozawa, Tsutomu,Takata, Toshikazu
, p. 1199 - 1202 (2005)
(Chemical Equation Presented) Rotaxanes possessing a cinnamyl ester group at the axle terminal were prepared. The terminal end-cap was modified with a bulky malonate ester in excellent yield by the Tsuji-Trost allylation reaction, which was carried out in the presence of a palladium catalyst.
End-capping of a pseudorotaxane via diels-alder reaction for the construction of C60-terminated [2]rotaxanes
Sasabe, Hisahiro,Kihara, Nobuhiro,Furusho, Yoshio,Mizuno, Kazuhiko,Ogawa, Akiya,Takata, Toshikazu
, p. 3957 - 3960 (2007/10/03)
(Chemical Equation Presented) The Diels-Alder reaction of various dienophiles such as C60 with a pseudorotaxane having a sultine moiety afforded corresponding [2]-rotaxanes in moderate yields. The introduction of a porphyrin moiety on the wheel
