79841-66-0Relevant academic research and scientific papers
CHEMISTRY OF SILYL THIOKETONES. Part 6. SYNTHESIS OF 5-MEMBERED SILYL-HETEROCYCLES VIA 1,3-DIPOLAR CYCLOADDITION TO ARYL SILYL THIOKETONES
Bonini, Bianca F.,Maccagnani, Gaetano,Mazzanti, Germana,Abdel-lateef, Ghamel,Atwa, Achmed,et al.
, p. 47 - 57 (2007/10/02)
Aryl silyl thioketones react with 1,3-dipoles (nitriloxides, nitrilimine and nitrile ylide) to give regiospecifically silyl thiaheterocycles.These cycloadducts undergo desilylation leading either to ring fragmentation products or to the H-substituted heterocycles.
Silyl Thioketones and Silylated Thiirans
Bonini, Bianca F.,Mazzanti, Germana,Sarti, Sauro,Zanirato, Paolo,Maccagnani, Gaetano
, p. 822 - 823 (2007/10/02)
The preparation of silyl thioketones, and their reactions leading to silylated thiirans and other hitherto unknown silylated heterocycles, are reported.
