79847-83-9

Upstream product

• 39637-99-5 (S)-(+)-2-methoxy-2-trifluoromethyl-2-phenylacetyl chloride 
• 79847-79-3 (S)-(-)-2-methyl-1-decanol 
• 18675-24-6 2-methyldecan-1-ol 
• 142348-87-6 2-methyldec-2-enal dimethyl acetal 
• 113709-48-1 ethyl (R,S)-2-methyldec-2-enoate 
• 126784-41-6 ethyl (R,S)-2-methyldecanoate 
• 80698-14-2 (R)-(+)-2-methyldecan-1-ol 
• 20445-33-4 (R)-methoxytrifluoromethylphenylacetyl chloride 

Relevant academic research and scientific papers

Application of modified Mosher's method for primary alcohols with a methyl group at C2 position.

The absolute configurations of a series of primary alcohols possessing a branched methyl group at C2 position were examined on the basis of a modified Mosher's method proposed by Minale et al. It was revealed that in many cases the absolute configurations

A Chemoenzymatic Synthesis of Enantiomerically Pure (R)- and (S)-2-Methyldecan-1-ol

(R)- and (S)-methyldecan-1-ol 3a has been prepared in >98percent enantiomeric excess (ee) by transesterification with vinyl acetate in chloroform in the presence of Pseudomonas fluorescens lipase.Oxidation of the alcohol 3a affords nearly optically pure 2-methyldecanoic acid 3b.

CHIRAL SYNTHESIS OF (2S,3S,7S)-3,7-DIMETHYLPENTADECAN-2-YL ACETATE AND PROPIONATE, POTENTIAL SEX PHEROMONE COMPONENTS OF THE PINE SAW-FLY NEODIPRION SERTIFER (GEOFF.)

A synthesis of (2S,3S,7S)-3,7-dimethylpentadecan-2-yl acetate (2) and propionate (3) is described. (2S)-2-Methyldecan-1-yl lithium (5) was reacted with (3S,4S)-3,4-dimethyl-γ-butyrolactone (6) to yield the ketoalcohol 19 which upon Huang-Minlon reduction furnished (2S,3S,7S)-3,7-dimethylpentadecan-2-ol (1).Acylations gave the esters 2 and 3.The (2S)-2-methyldecan-1-yl lithium was obtained via asymmetric synthesis.The chiral lactone 6 was obtained from (2S,3S)-trans-2,3-epoxybutane and dimethylmalonate.