79849-80-2Relevant academic research and scientific papers
SYNTHESE, STRUCTURE ET REACTIVITE DE SELENOXYDES DERIVES DU RIBOSE ET DE L'ADENOSINE: NOUVELLE VOIE D'ACCES AUX RIBOFURANOSIDES INSATURES EN C(4')-C(5')
Boullais, C.,Zylber, N.,Zylber, J.,Guilhem, J.,Gaudemer, A.
, p. 759 - 766 (2007/10/02)
A new method for the introduction of an exocyclic double bond at C(4)-C(5) of ribose or adenosine uses the easy conversion of selenoxides to the corresponding alkenes by thermal elimination.Ribose, adenosine and their 2',3'-O-isopropylidene derivatives ha
SIMPLE SYNTHESIS OF 9-(5-DEOXY-β-D-ERYTHRO-PENT-4-ENOFURANOSYL)ADENINE FROM ADENOSINE BY SELENOXIDE FRAGMENTATION
Takaku, Hiroshi,Nomoto, Tadaaki,Kimura, Kenji
, p. 1221 - 1224 (2007/10/02)
5'-Se-(2-Nitrophenyl)-5'-selenoadenosine (3) was selectively synthesized by the reaction of adenosine with 2-nitrophenylselenocyanate and tri-n-butylphosphine.The selenide 3 was oxidised by treatment with excess hydrogen peroxide to the corresponding sele
