79893-39-3Relevant academic research and scientific papers
Non-polar halogenated natural products bioaccumulated in marine samples. II. Brominated and mixed halogenated compounds
Vetter, Walter,Jun, Wu
, p. 423 - 431 (2003)
Several identified and potential natural brominated bioaccumulative compounds were studied in this work. 4,6-dibromo-2-(2′,4′-dibromo)phenoxyanisole (BC-2) previously detected in Australian marine mammals and isolated from sponges, was synthesized. Two by
An improved process for the preparation of 5-bromo-2-methoxyresorcinol
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, (2008/06/13)
This invention is concerned with an improved process for metallating 2,4,6-tribromoanisole 1and reacting this intermediate lithio species with various electrophiles for example the trialkoxy borates which an example is trimethylborate, the improvement comprising carrying out the reaction under heterogenous conditions. This product is oxidatively converted to the compound 5-bromo-2-methoxy-resorcinol 2, which is in turn converted to the known 2-methoxy-resorcinol 3. The process and intermediate are useful in the synthesis of platelet activating factor antagonist thiazolium, 3-[[3-[[hydroxy[2-methoxy-3-(tetradecyloxy) phenoxy]phosphinyl]oxy]phenyl]methyl]-5-methyl-, hydroxide, inner salt CA of U. S. Patent 4983592 (1991).
