79909-76-5

Basic information

• Product Name: (E)-3-phenyl-thioacrylic acid S-methyl ester
• Synonyms: (E)-3-phenyl-thioacrylic acid S-methyl ester
• CAS NO: 79909-76-5
• Molecular Weight: 178.255
• Mol File: 79909-76-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-3-phenyl-thioacrylic acid S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-phenyl-thioacrylic acid S-methyl ester(79909-76-5)
• EPA Substance Registry System: (E)-3-phenyl-thioacrylic acid S-methyl ester(79909-76-5)

Safety Data

• Hazardous Substances Data: 79909-76-5(Hazardous Substances Data)

Upstream product

• 88925-11-5 S-methyl bromoethanethiolate 
• 100-52-7 benzaldehyde 
• 74-93-1 methylthiol 
• 102-92-1 Cinnamoyl chloride 
• 15081-73-9 3,3-Bis(methylthio)-1-phenyl-2-propenol 
• 3908-55-2 Trimethyl(methylthio)silane 
• 103-26-4 Methyl cinnamate 
• 13636-88-9 3,3-bis(methylthio)-1-phenylprop-2-en-1-one 
• 140-10-3 (E)-3-phenylacrylic acid 
• 126712-09-2 1,1-bis(methylthio)-2-trimethylsilylethene 
• 22987-05-9 (Triphenylphosphoranyliden)thioessigsaeure-S-methylester 

Downstream Products

• 917590-80-8 (2S,3S,1'S)-3-hydroxy-2-(1-phenyl-ethyl)-octanoic acid methyl ester 
• 917590-74-0 (3S)-3-phenyl-thiobutyric acid S-methyl ester 

Relevant articles and documents

Highly versatile enantioselective conjugate addition of grignard reagents to α,β-unsaturated thioesters

Herein, we report efficient catalysts for the asymmetric copper-catalyzed conjugate addition of Grignard reagents to α,β-unsaturated thioesters. MeMgBr adds to aromatic α,β-unsaturated thioesters with excellent enantioselectivities and moderate to good yi

Ketene dithioacetals in organic synthesis: Synthesis of silyl ketene dithioacetal and some reactions with substituted benzaldehydes

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The Synthesis of 5-Alkylidenefuran-2(5H)-ones

5-Alkylidenefuran-2(5H)-ones can be synthesized efficiently from S-methyl 5-oxo-2,5-dihydro-furanylidenealkanethioates by treatment with Raney nickel.The ylidenealkanethioates are prepared from the Wittig reactions between cyclic anhydrides and (methylthi