79917-47-8Relevant academic research and scientific papers
Arylimidodimagnesium Reagents. X. The Mild Reagent Derived from 2-Aminopyridine and Formation of Highly Reactive Azoxypyridines in the Reaction with Nitrobenzenes
Okubo, Masao,Sugimori, Chieko,Tokisada, Mitsunao,Tsutsumi, Toshiki
, p. 1644 - 1646 (2007/10/02)
The reaction of iminodimagnesium reagent derived from 2-amino-4-methylpyridine with nitrobenzenes was examined.The relative yields of the azoxypyridine formed via condensation and the azopyridines via deoxygenation and oxidative dimerization were explained in terms of weak electron-accepting ability of the azoxypyridine.
Conversion of a Primary Amino Group into a Nitroso Group. Synthesis of Nitroso-Substituted Heterocycles
Taylor, Edward C.,Tseng, Chi-Ping,Rampal, Jang B.
, p. 552 - 555 (2007/10/02)
2-Aminopyridine, 2-amino-4-methylpyridine, 1-aminoisoquinoline, 2-aminopyrimidine, and 2-aminopyrazine have been converted to the corresponding nitroso compounds by reaction with dimethyl sulfide and N-chlorosuccinimide, deprotonation of the resulting sul
