79926-76-4Relevant academic research and scientific papers
New options for the reactivity of the burgess reagent with epoxides in both racemic and chiral auxiliary modes - Structural and mechanistic revisions, computational studies, and application to synthesis
Leisch, Hannes,Sullivan, Bradford,Fonovic, Branden,Dudding, Travis,Hudlicky, Tomas
experimental part, p. 2806 - 2819 (2009/09/25)
The reaction of the chiral auxiliary version of the Burgess reagent with epoxides yields diastereomeric pairs of sulfamldates, which, lead, to cis and trans amino alcohols in each, enantiomeric series. Experimental and spectral, details are provided for a
REACYIONS OF 1-ALKOXYCARBONYLAZIRIDINES WITH NUCLEOPHILIC REAGENTS
Baranov, S. V.,Mochalin, V. B.
, p. 779 - 782 (2007/10/02)
1-Methoxycarbonylaziridines react under mild conditions with a number of nucleophilic reagents such as water, acids, alcohols, and amines with opening of the aziridine ring.In the case of 7-methoxycarbonyl-7-azabicycloheptane it was shown by PMR sp
