79979-60-5Relevant academic research and scientific papers
BIS(TERT-BUTYLSULFONYL)ACETYLENE AS A GENERAL SYNTHETIC EQUIVALENT OF ALKYNES IN DIELS-ALDER CHEMISTRY. II: REDUCTIVE AND ALKYLATIVE DESULFONYLATIONS OF BICYCLIC 1-ALKYL-2-(TERT-BUTYLSULFONYL)ETHENES
Virgili, Marina,Belloch, Jordi,Moyano, Albert,Pericas, Miquel A.,Riera, Antoni
, p. 4583 - 4586 (2007/10/02)
Both reductive and alkylative desulfonylations of bicyclic vinyl sulfones derived from Diels-Alder cycloadducts of bis(tert-butylsulfonyl)acetylene (1) are described.These transformations establish the synthetic equivalence of 1 with acetylene, 1-alkynes
KETENE-ANTHRACENE ADDUCT, A PRECURSOR OF SUBSTITUTED ACETYLENES
Tarnchompoo, Bongkoch,Thebtaranonth, Yodhathai,Utamapanya, Suchada,Kasemsri, Prapani
, p. 1241 - 1242 (2007/10/02)
The ketene-anhracene adduct 1 serves as a good precursor in the synthesis of substituted acetylenes, in wich the key step is the retro Diels-Alder reaction.
