799812-76-3

Upstream product

• 1042289-75-7 rac-1,2-dipalmitoylglycerol 
• 555-44-2 glyceroltripalmitate 
• 99-24-1 methyl galloate 
• 121-79-9 Propyl gallate 
• 1486-47-1 3,4,5-tris(benzyloxy)benzoyl chloride 
• 408539-81-1 3,4,5-tris-benzyloxy-benzoic acid-(2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester) 
• 408338-02-3 3,4,5-tris-benzyloxy-benzoic acid-(2,3-dihydroxy-propyl ester) 
• 1486-48-2 3,4,5-tribenzyloxybenzoic acid 
• 261729-41-3 1,2-dipalmitoyl(3,4,5-tri-O-benzylgalloyl)glycerol 

Relevant academic research and scientific papers

Solvent-free enzymatic synthesis of 1,2-dipalmitoylgalloylglycerol: Characterization and optimization of reaction condition

A novel diacylglycerol-based galloyl structured lipid, 1,2-dipalmitoylgalloylglycerol (DPGG), was synthesized using the enzymatic transesterification of propyl gallate (PG) and tripalmitin under solvent-free condition. An immobilized and commercially available food-grade Candida antarctica lipase B, Lipozyme 435, was used as the biocatalyst. The reaction variables that affect the yield of DPGG were optimized using a 33 full factorial design. At 70 °C, DPGG was obtained at a yield of 33.0 ± 2.0% with PG conversion at 44.8 ± 1.8% when the following condition was used: 25 substrate molar ratio of tripalmitin to PG, 120 h reaction time, and 25% enzyme load relative to the total substrate weight. The structure of reaction product was elucidated using Fourier-transform infrared spectroscopy (FT-IR), electrospray ionization high-resolution accurate-mass tandem mass spectrometry (ESI-HRAM-MS/MS), and 1D and 2D nuclear magnetic resonance spectroscopy (NMR). The effects of different lipases and galloyl donors/acceptors on the transesterification were also investigated.

Synthesis and characterization of a series of novel phenol- and polyphenol-based glycerolipids

A building block approach was used to design a modular synthetic route for the preparation of novel glycerolipids with phenolic and polyphenolic headgroups. Based on this scheme, it is possible to vary the substitution pattern of the headgroup, the stereo

Synthesis, structure, and thermal properties of 1,2-dipalmitoylgalloylglycerol (DPGG), a novel self-adhering lipid

A novel diacyl glycerol-based lipid with a polyphenolic head group has been synthesized and characterized. X-ray diffraction experiments show that this lipid, 1,2-dipalmitoylgalloylglycerol (DPGG), hydrates to form gel phase bilayers at 20°C with extremel