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Addition of Aldehydes to Activated Double Bonds, XXX. - Synthesis of Unsymmetrical γ-Polyketones, 4,7,10-Trioxo Esters, and 4,7,10-Trioxo Nitriles
Stetter, Hermann,Mertens, Alfred
, p. 1550 - 1560 (2007/10/02)
Thiazolium salt catalyzed additions of aldehydes to the vinyl ketones 7-12 lead to γ-polyketones 5, 6, 13-28, 38-49, 4,7,10-trioxo esters 29-33, and 4,7,10-trioxo nitriles 34-37.The vinyl ketones 7-12 were obtained by repeated thiazolium salt catalyzed ad
