79991-78-9Relevant articles and documents
Acyl Nitrene Cyclisations in Antibiotics. Synthesis of 6''-Aminogentamicin C2
Wright, J. J. Kim,Albarella, James A.,Lee, Paul
, p. 523 - 527 (1982)
The insertion reaction of an acyl nitrene has been used to functionalize the branched-chain sugar moiety, garosamine, of the antibiotic gentamicin C2.Contrary to expectations based on intermolecular reactions in simple systems, insertion into the branched