Acyl Nitrene Cyclisations in Antibiotics. Synthesis of 6''-Aminogentamicin C2

DOI: 10.1021/jo00342a030

Source and publish data:

Journal of Organic Chemistry p. 523 - 527 (1982)

Update date:2022-08-06

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Authors:

Wright, J. J. Kim

Albarella, James A.

Lee, Paul

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Article abstract of DOI:10.1021/jo00342a030

The insertion reaction of an acyl nitrene has been used to functionalize the branched-chain sugar moiety, garosamine, of the antibiotic gentamicin C2.Contrary to expectations based on intermolecular reactions in simple systems, insertion into the branched

Full text of DOI:10.1021/jo00342a030

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