80037-90-7

Basic information

• Product Name: 2H-Isoindol-2-yloxy, 1,3-dihydro-1,1,3,3-tetramethyl-
• CAS NO: 80037-90-7
• Molecular Formula: C12H16NO
• Molecular Weight: 190.265
• Mol File: 80037-90-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2H-Isoindol-2-yloxy, 1,3-dihydro-1,1,3,3-tetramethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Isoindol-2-yloxy, 1,3-dihydro-1,1,3,3-tetramethyl-(80037-90-7)
• EPA Substance Registry System: 2H-Isoindol-2-yloxy, 1,3-dihydro-1,1,3,3-tetramethyl-(80037-90-7)

Safety Data

• Hazardous Substances Data: 80037-90-7(Hazardous Substances Data)

Upstream product

• 159063-67-9 6-methylene-1,4-oxathiepan-7-one 
• 89429-29-8 2-(1',1'-dimethylprop-2'-enoxy)-1,1,3,3-tetramethylisoindoline 
• 5689-12-3 1,1,3,3-tetramethylindane-2-one 

Downstream Products

• 81913-48-6 2-(2-tert-butoxy-1-phenylethoxy)-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole 
• 80037-95-2 2-methoxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole 
• 185-94-4 bicyclo[2.1.0]pentane 
• 134278-19-6 cis-1,3-bis(1',1',3',3'-tetramethyl-1',3'-dihydroisoindolin-2'-yloxyl)cyclopentane 
• 134278-20-9 trans-1,3-bis(1',1',3',3'-tetramethyl-1',3'-dihydroisoindolin-2'-yloxyl)cyclopentane 
• 137601-43-5 1,1,3,3-tetramethyl-2-(2'-methylcyclohex-2'-enyloxy)-1,3-dihydroisoindole 
• 137601-42-4 1,1,3,3-tetramethyl-2-(3'-methylcyclohex-2'-enyloxy)-1,3-dihydroisoindole 
• 138062-41-6 cis-1,3-bis(1',1',3',3'-tetramethyl-1',3'-dihydroisoindolin-2'-yloxyl)-2-(diphenylmethylidene)clopentane 
• 138062-40-5 trans-1,3-bis(1',1',3',3'-tetramethyl-1',3'-dihydroisoindolin-2'-yloxyl)-2-(diphenylmethylidene)clopentane 
• 89429-39-0 2-allyloxy-1,1,3,3-tetramethyl-1,3-dihydroisoindole 
• 89429-27-6 2-(2'-t-butoxyl-1'-methylethoxy)-1,1,3,3-tetramethylisoindoline 
• 89429-42-5 2-(2'-t-butoxypropoxy)-1,1,3,3-tetramethylisoindoline 
• 96519-47-0 t-butyl-2-(1,1,3,3,-tetramethylisoindolin-2-yloxy)ethanoate 
• 96519-48-1 1,1-dimethyl-2-(1,1,3,3,-tetramethylisoindolin-2-yloxy)ethyl ethanoate 

Relevant articles and documents

The reactivity of nitroxides towards alkenes

At elevated temperatures, nitroxides (e.g. 1,1,3,3-tetramethyl-2,3- dihydroisoindol-2-yloxyl) undergo a slow addition reaction with acrylonitrile, methyl acrylate and styrene to give the bis-nitroxide adducts. With alkenes containing an allylic hydrogen such as methyl methacrylate and 6-methylene-1,4-oxathiepan-7-one, the major reaction observed was hydrogen abstraction. The resulting hydroxylamines can be trapped as Michael addition products. (C) 2000 Elsevier Science Ltd.

The Reactions of t-Butoxyl with Unsaturated Hydrocarbons: Structure and Reactivity of Allylic Radicals

A radical trapping technique employing 1,1,3,3-tetramethylisoindolin-2-yloxyl (1) as scavenger has been used to study the reactions of t-butoxy radicals with propene, 2-methylpropene, but-1-ene, (E)- and (Z)-but-2-ene, 3-methylbut-1-ene, buta-1,3-diene and 2-methylbuta-1,3-diene.Relative rates of double bond addition and of allylic hydrogen abstraction have been measured and are discussed, as are the relative stabilities of the products formed.The allylic radicals generated in these systems react with (1) mainly by coupling at the more substituted terminus of the radical ? system.Substituent effects on this regioselectivity may be explained in terms of the electrophilicity of (1).