80070-89-9

Basic information

• Product Name: 2-BR-Z-CL
• Synonyms: 2-BR-Z-CL;2-BROMOBENZYL CHLOROFORMATE
• CAS NO: 80070-89-9
• Molecular Formula: C₈H₆BrClO₂
• Molecular Weight: 249.49
• Mol File: 80070-89-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-BR-Z-CL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BR-Z-CL(80070-89-9)
• EPA Substance Registry System: 2-BR-Z-CL(80070-89-9)

Safety Data

• Hazardous Substances Data: 80070-89-9(Hazardous Substances Data)

Upstream product

• 18982-54-2 o-bromobenzyl alcohol 
• 500372-18-9 O-(2-bromobenzyl) 2-methyl carbonothioate 
• 75-44-5 phosgene 

Downstream Products

• 80070-87-7 bis(o-bromobenzyl) peroxydicarbonate 

Relevant articles and documents

Benzyl chloroformate (CbzCl) synthesis using carbon monoxide as a carbonyl source

A novel non-phosgene synthetic method for benzyl chloroformate (CbzCl) was established. S-Methyl O-benzyl carbonothioates were prepared by the carbonylation of benzyl alcohols with carbon monoxide and sulfur (or carbonyl sulfide) in the presence of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) followed by esterification using methyl iodide in good yields. Then, CbzCl derivatives were successfully synthesized by the chlorination of S-methyl O-benzyl carbonothioates using sulfuryl chloride in excellent yields.

KINETIC LAWS OF THE THERMAL DECOMPOSITION OF SUBSTITUTED DIBENZYL PEROXYDICARBONATES IN ORGANIC MEDIA

1.The relative extents of unimolecular and induced decomposition in thethermolysis of substituted dibenzyl peroxydicarbonates were investigated.They are influenced substatially by the reaction medium and also by the structure of the peroxydicarbonate take