80070-89-9Relevant academic research and scientific papers
Benzyl chloroformate (CbzCl) synthesis using carbon monoxide as a carbonyl source
Mizuno, Takumi,Takahashi, Junko,Ogawa, Akiya
, p. 10011 - 10015 (2007/10/03)
A novel non-phosgene synthetic method for benzyl chloroformate (CbzCl) was established. S-Methyl O-benzyl carbonothioates were prepared by the carbonylation of benzyl alcohols with carbon monoxide and sulfur (or carbonyl sulfide) in the presence of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) followed by esterification using methyl iodide in good yields. Then, CbzCl derivatives were successfully synthesized by the chlorination of S-methyl O-benzyl carbonothioates using sulfuryl chloride in excellent yields.
Non-phosgene synthesis of benzyl chloroformate (CbzCl)
Mizuno, Takumi,Takahashi, Junko,Ogawa, Akiya
, p. 7765 - 7767 (2007/10/03)
A novel synthetic method for benzyl chloroformate (CbzCl) using carbon monoxide or carbonyl sulfide as a carbonyl source was established. Benzyl chloroformate was successfully synthesized by the chlorination using sulfuryl chloride of S-methyl O-benzyl carbonothioate, which was prepared by the carbonylation of benzyl alcohol with carbon monoxide and sulfur (or carbonyl sulfide) in the presence of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) followed by esterification using methyl iodide.
KINETIC LAWS OF THE THERMAL DECOMPOSITION OF SUBSTITUTED DIBENZYL PEROXYDICARBONATES IN ORGANIC MEDIA
Ovchinnikova, Yu. I.,Fomin, V. A.,D'yachkov, A. I.,Etlis, V. S.
, p. 2031 - 2036 (2007/10/02)
1.The relative extents of unimolecular and induced decomposition in thethermolysis of substituted dibenzyl peroxydicarbonates were investigated.They are influenced substatially by the reaction medium and also by the structure of the peroxydicarbonate take
