80081-45-4

Basic information

• Product Name: [S-(R*,R*)]-tartarohydrazide
• Synonyms: [S-(R*,R*)]-tartarohydrazide;(2S,3S)-2,3-Dihydroxybutanedioic acid dihydrazide
• CAS NO: 80081-45-4
• Molecular Formula: C4H10N4O4
• Molecular Weight: 178.1466
• EINECS: 279-391-7
• Mol File: 80081-45-4.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 724.9°C at 760 mmHg
• Flash Point: 392.2°C
• Appearance: /
• Density: 1.626g/cm³
• Vapor Pressure: 2.92E-24mmHg at 25°C
• Refractive Index: 1.608
• CAS DataBase Reference: [S-(R*,R*)]-tartarohydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: [S-(R*,R*)]-tartarohydrazide(80081-45-4)
• EPA Substance Registry System: [S-(R*,R*)]-tartarohydrazide(80081-45-4)

Safety Data

• Hazardous Substances Data: 80081-45-4(Hazardous Substances Data)

Usage

General Description

[S-(R*,R*)]-tartarohydrazide is a chemical compound that belongs to the class of hydrazines. It has two chiral centers and exists as a pair of enantiomers. [S-(R*,R*)]-tartarohydrazide is commonly used in organic synthesis as a chiral auxiliary or as a resolving agent for the separation of racemic mixtures. It is also used in the preparation of optically active compounds and in the study of stereochemistry. Additionally, [S-(R*,R*)]-tartarohydrazide has potential applications in medicine and pharmaceuticals due to its ability to interact with biological molecules and influence their stereochemical properties. Overall, this compound has diverse uses in the fields of chemistry, pharmacology, and biochemistry.

InChI:InChI=1/C4H10N4O4/c5-7-3(11)1(9)2(10)4(12)8-6/h1-2,9-10H,5-6H2,(H,7,11)(H,8,12)

Upstream product

• 87-91-2 diethyl (2R,3R)-tartrate 
• 38115-91-2 (R,R)-(+)-tartaric acid N,N'-dimethyldiamide 
• 87-69-4 tartaric acid 
• 408332-88-7 Diethyl tartrate 
• 405897-14-5 dimethyl tartrate 
• 608-68-4 dimethyl L-tartrate 

Downstream Products

• 143661-74-9 (2S,3S)-2,3-dihydroxybutanedioyl bis(salicylaldehyde hydrazone) 
• 957265-46-2 C₂₂H₂₂N₄O₄ 
• 143729-34-4 tartaric-bis(p-nitrophenyl)hydrazone 

Relevant articles and documents

Ultra-fast self-healing PVA organogels based on dynamic covalent chemistry for dye selective adsorption

Ultra-fast self-healing organogels based on dynamic covalent chemistry for dye adsorption were prepared from polyvinyl alcohol (PVA), 4-formylphenylboronic acid (FPBA), and tartaric acid dihydrazide (TDH) by an effective in situ reaction approach. The relative xerogels can adsorb methylene blue selectively with high efficiency. The boronate ester bonds and acylhydrazone bonds endow organogels with a very fast self-healing property. What's more, the chirality can be transferred from TDH to the organogels. The organogels obtained from l-TDH and d-TDH show opposite chirality according to the circular dichroism spectra.

Li+-induced selective gelation of discrete homochiral structural isomers derived from l-tartaric acid

Two chiral structural isomers have been synthesized by molecular engineering of l-tartaric acid. In the presence of LiOH isomer 1 forms a thermally stable, fluorescent gel which exhibits interesting nano-cluster morphology, anomalous optical and rheological properties whilst 2 forms a non-fluorescent solution under similar conditions. The current-voltage (I-V) curve followed a non-linear trend, rationally in close proximity to the diode characteristic curve. This journal is the Partner Organisations 2014.

Synthesis of optically active macrolides with hydrazide fragments from tetrahydropyran and L-(+)-tartaric acid derivatives

The synthesis of two potentially useful optically active 23- and 30-membered macrolides containing a 1,2-diol system and dihydrazide fragments was developed starting from tetrahydropyran. It was based on [1+1]-condensation of 7-oxooctyl-7-oxooctanoate and bis(7-oxooctyl)hexanedioate with L-(+)-tartaric acid hydrazide.