801-28-5Relevant academic research and scientific papers
Reactions of perfluoro(5-aza-4-nonene) with hydrazine and some its derivatives
Furin,Chi, Ki-Wan,Protsuk,Lopyrev
, p. 1621 - 1628 (2001)
The reaction of perfluoro(5-aza-4-nonene) with hydrazine hydrate in tetrahydrofuran at 0-20°C in the presence of triethylamine yields 2,5-bis(heptafluoropropyl)-1H-1,2,4-triazole; under similar conditions perfluoro(5-aza-4-nonene) reacts with arylhydrazin
Solvolyis reactions of perfluoro-5-aza-4-nonene, C3 F7-CF=N-C4F9
Siedle,Webb, Robert J.,Newmark,Brostrom, Myles,Weil, David A.,Erickson, Kristin,Behr, Fred. E.,Young Jr., Victor G.
, p. 175 - 182 (2007/10/03)
Hydrolysis of the imine perfluoro-5-aza-4-nonene, C3 F7-CF=N-C4F9, in ether was studied by several spectroscopic techniques including 17O NMR. The initial product is C3F7 -CO-NH-
Perfluoro(5-aza-4-nonene) in the synthesis of heterocyclic compounds containing a perfluoropropyl group
Furin,Kiriyanko,Lopyrev,Zhuzhgov,Protsuk
, p. 109 - 116 (2007/10/03)
Reactions of perfluoro(5-aza-4-nonene) with isopropylamine, tert-butylamine, 2-amino-6-bromo-benzothiazole, and 2-amino-1-methylbenzimidazole in THF in the presence of triethylamine gave the corresponding diazetine derivatives. Reactions of the title compound with difunctional reagents, such as benzamidine, acetamidine, phenylhydrazine, pentafluorophenylhydrazine, and heprafluorobutyrohydrazide, resulted in formation of 1,3,5-triazine and 1,2,4-triazole derivatives. Possible reaction pathways, the role of triethylamine, and spectral parameters of the products are discussed. * This study was financially supported by the Russian Foundation for Basic Research (project no. 96-03-33047).
