80106-30-5

Upstream product

• 7681-84-7 tetrahydrofuran-2-carbaldehyde 

Downstream Products

• 124781-67-5 (E,E)-1-(Phenylseleno)octa-4,6-diene 
• 90344-15-3 (E,E)-octa-4,6-dien-1-ol tosylate 
• 124781-69-7 Dimethyl (3α,6α)-6-Methyl-3-<3-(phenylseleno)-propyl>-4-cyclohexene-1,2-dicarboxylate 
• 124781-81-3 (5α,8α)-5,8-Dihydro-8-methyl-2-phenyl-5-<3-(phenylseleno)propyl>-s-triazolo<1.2-a>pyridazine-1,3-dione 
• 124781-88-0 (4α,5aβ,8aβ)-4-Methyldodecahydro-2-phenyl-2,3a,8b-triaza-as-indacene-1,3-dione 
• 124781-80-2 (1α,2α,3α,6α)-6-Methyl-3-<3-(phenylseleno)propyl>-4-cyclohexene-1,2-dicarboxylic Anhydride 
• 90367-62-7 (1S,4aR,7S,8S,8aS)-8-{2-[(2R,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ol 
• 90410-99-4 (1S,4aS,7R,8R,8aR)-8-{2-[(2R,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ol 
• 90344-14-2 C₄₄H₅₈O₅S₃Si 
• 90344-19-7 8-{1-Benzenesulfonyl-2-[(2S,4R,6R)-4-(tert-butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one 
• 90344-22-2 (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-{2-[(2R,4R)-4-(tert-butyl-diphenyl-silanyloxy)-6-oxo-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester 
• 90344-20-0 (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-{2-[(2R,4R,6R)-4-(tert-butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester 
• 90344-21-1 (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-{2-[(2R,4R,6R)-4-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester 
• 90344-10-8 (3aR,4R,7S,7aS)-4-(3-Benzenesulfonyl-propyl)-7-methyl-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione 

Relevant academic research and scientific papers

Mixed metal base LICKOR as key reagent in the synthesis of conjugate alkadien-1-ols. A new route to an insect attractant

Tetrahydrofurfuryl alcohol has been oxidized to the corresponding aldehyde (1) using TRAP and NMO. Subsequent Wittig reaction afforded 2-alk- 1-enyltetrahydrofurans (2 and 3) that can be metalated with Schlosser's reagent LICKOR. The base promotes the 1,4-eliminative ring fission, affording conjugate alkadien-1-ols (4 and 5) with high all E stereoselectivity. In the case of 2-pent-1-enyltetrahydrofuran, elimination reaction gives (4E,6E)- nona-4,6-dien-1-ol (5), which is structurally related to two sex pheromone components of the Caribbean fruit fly, Anastrepha suspensa.