80120-67-8Relevant academic research and scientific papers
Synthesis of Allyl and Dienyl Sulphones via Iodosulphonylation of Conjugated Dienes
Barluenga, Jose,Martinez-Gallo, Jose M.,Najera, Carmen,Fananas, Francisco J.,Yus, Miguel
, p. 2605 - 2610 (2007/10/02)
The iodosulphonylation of conjugated dienes with sodium or mercury(II) toluene-p-sulphinate and iodine yields δ-iodoalkenyl sulphones stereoselectively.These compounds undergo stereospecific dehydrohalogenation to afford dienyl sulphones and nucleophilic
REACTION OF 1,3-DIENES WITH ARYLSULFONYL THIOCYANATES
Tanaskov, M. M.,Starodub, P. E.,Stadnichuk, M. L.,Tanaskova, E. A.
, p. 1609 - 1615 (2007/10/02)
At room temperature arylsulfonyl thiocyanates add to conjugated dienes with the formation of 1,4-addition products.In all cases the organic sulfonyl radical is fixed at the least substituted carbon atom of the 1,3-diene system.In reaction with triethylamine or sodium ethoxide the adducts which form eliminate thiocyanic acid with the formation of conjugated dienyl sulfones.
