801294-25-7

Basic information

• Product Name: 2-Cyclohexen-1-ol,2-methyl-5-(1-methylethenyl)-,methanesulfonate(9CI)
• Synonyms: 2-Cyclohexen-1-ol,2-methyl-5-(1-methylethenyl)-,methanesulfonate(9CI)
• CAS NO: 801294-25-7
• Molecular Formula: C11H18O3S
• Molecular Weight: 0
• Product Categories: METHYL
• Mol File: 801294-25-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Cyclohexen-1-ol,2-methyl-5-(1-methylethenyl)-,methanesulfonate(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-ol,2-methyl-5-(1-methylethenyl)-,methanesulfonate(9CI)(801294-25-7)
• EPA Substance Registry System: 2-Cyclohexen-1-ol,2-methyl-5-(1-methylethenyl)-,methanesulfonate(9CI)(801294-25-7)

Safety Data

• Hazardous Substances Data: 801294-25-7(Hazardous Substances Data)

Upstream product

• 6485-40-1 (R)-Carvone 
• 99-48-9 (4R,6R)-carveol 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 113159-65-2 2-((1S,5R)-5-Isopropenyl-2-methyl-cyclohex-2-enyl)-2-prop-2-ynyl-malonic acid dimethyl ester 

Relevant articles and documents

Synthesis and some transformations of (-)-carveol

Reduction of the oxo group in (-)-carvone with LiAlH4, NaBH4, and (i-Bu)2AlH was performed. It was found that the reduction with the system CeCl3 ? 7 H2O-NaBH4 in methanol at 20°C is the most practical procedure for the synthesis of (-)-carveol. Solvolysis of (-)-carvyl methanesulfonate gave products of SN2 and SN2' replacement of the methylsulfonyloxy group, the latter slightly prevailing. Overman rearrangement of (-)-carveol resulted in the formation of the corresponding trichloroacetamide derivative, and intramolecular iodoetherification of the title compound afforded 6-iodomethyl-2,6-dimethyl-7-oxabicyclo[3.2.1]oct-2-ene. Pleiades Publishing, Ltd., 2009.