80138-53-0

Upstream product

• 7785-70-8 (+)-α-pinene 
• 127-65-1 chloroamine-T 
• 69363-09-3 (1S,2S,3R,5S)-3-amino-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 69363-09-3 (1S,2S,3R,5S)-3-amino-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol 

Relevant academic research and scientific papers

A practical method for preparation of optically pure oxazaborolidines from α-pinene

(1S,2S,3R,5S)- and (1S,2S,3R,5S)-3-amino-2-hydroxypinane (1 and 2) were prepared from the corresponding α-pinene in optically pure form. They and their derivatives reacted with various organoborane compounds. A variety of chiral oxazaborolidines 3a-e and 4 were obtained in high yield.

REACTIONS OF UNSATURATED TERPENE COMPOUNDS WITH CHLORAMINE-T. PART I. (1R,2S,4S)-1-HYDROXY-2-(p-TOLUENESULFONAMIDO)-p-MENTHANE AND (1S,2S,3R)-2-HYDROXY-3-(p-TOLUENESULFONAMIDO)-PINANE

Reactions of p-menth-1-ene and α-pinene with chloramine-T in presence of catalytic quantities of OsO4 have been investigated.Homogeneous products were isolated, the structure of which was established on the basis of spectral analyses and chemical transfor