80189-28-2Relevant academic research and scientific papers
Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
Madro?ero, Diego,Mujica-Martinez, Cesar A.,Vázquez, Alfredo
, p. 33235 - 33244 (2021/12/09)
Lithium anions derived from O-carbonate-protected cyanohydrins undergo conjugate addition to cycloalkenones with the concomitant transfer of the alkoxycarbonyl group to produce tricarbonyl compounds. These products offer numerous possibilities for further
Enantioselective and diastereoselective syntheses of cyanohydrin carbonates
Belokon', Yuri N.,Clegg, William,Harrington, Ross W.,Ishibashi, Eisuke,Nomura, Hiroshi,North, Michael
, p. 9724 - 9740 (2008/02/12)
A new and general synthesis of alkyl cyanoformates is presented starting from the appropriate alcohol and oxalyl chloride. This is used to prepare enantiomerically pure cyanoformates from enantiomerically pure primary and secondary alcohols. Optimal condi
Eine neue Methode zur Herstellung von Nitrilen aus Aldoximen
Thomas, H. G.,Greyn, H. D.
, p. 129 - 130 (2007/10/02)
Aldoximes are dehydrated to nitriles in good yields by reaction with methyl or ethyl cyanoformates.The method can also be used for the synthesis of tert-butyl cyanoformate from tert-butyl oximinoacetate.
