80201-97-4Relevant articles and documents
Asymmetric Umpolung Hydrogenation and Deuteration of Alkenes Catalyzed by Nickel
Guo, Siyu,Wang, Xiuhua,Zhou, Jianrong Steve
supporting information, p. 1204 - 1207 (2020/02/04)
Nickel-catalyzed asymmetric hydrogenation of several types of alkenes proceeds in high enantioselectivity, using acetic acid or water as the hydrogen source and indium powder as electron donor. The scope of alkenes herein include α,β-unsaturated esters, n
Ruthenium-catalyzed 1,4-addition of organoboronic acids to α,β-unsaturated ketones
Shintani, Ryo,Hayashi, Tamio
, p. 724 - 725 (2008/12/21)
A ruthenium-catalyzed 1,4-addition of organoboronic acids to α,β-unsaturated ketones has been developed. The use of 2-(di-tert-butylphosphino)biphenyl as the ligand in combination with [RuCl 2(p-cymene)]2 complex catalyzes these reactions to selectively give 1,4-adducts in good yield by effectively suppressing Heck-type and reduced products. Copyright
Palladium catalyzed conjugate 1,4-addition of organoboronic acids to α,β-unsaturated ketones
Yamamoto, Tetsuya,Iizuka, Michiko,Ohta, Tetsuo,Ito, Yoshihiko
, p. 198 - 199 (2007/10/03)
1,4-Addition of arylboronic acids to α,β-unsaturated ketones was smoothly catalyzed by palladium(0) phosphine complexes with chloroform in the presence of base. It is remarked that the palladium(0) complexes have no catalytic activity in the absence of chloroform. The reaction proceeded without β-hydride elimination. Copyright
