802274-28-8

Upstream product

• 122-03-2 (4-isopropylbenzaldehyde) 
• 100-46-9 benzylamine 
• 2051-18-5 4-isopropylbenzyl chloride 

Downstream Products

• 136364-31-3 [Benzylamino-(4-isopropyl-phenyl)-methyl]-phosphonic acid 
• 135473-53-9 [Benzylamino-(4-isopropyl-phenyl)-methyl]-phosphonic acid diethyl ester 

Relevant academic research and scientific papers

Oxidation of N-benzylaldimines to N-benzylamides by MCPBA and BF3·OEt2

N-Benzylamides were obtained from the corresponding N-benzylaldimines in high yields. N-Benzylaldimines are readily prepared from the corresponding aldehydes with benzylamine. This procedure involves the oxidation of N-benzylaldimines with MCPBA with BF3·OEt2. In this reaction, the reaction presumably follows an internal hydrogen abstraction to provide only N-benzylamide.

ORGANIC PHOSPHORUS COMPOUNDS 94 PREPARATION, PHYSICAL AND BIOLOGICAL PROPERTIES OF AMINO-ARYLMETHYLPHOSPHONIC- AND -PHOSPHONOUS ACIDS

The preparation, physical and spectroscopic properties of amino-arylmethylphosphonic- and -phosphonous acids, the phosphorus analogues of phenylglycine, are described.It is shown that several of the compounds prepared exhibit antifungal activity at 200 ppm.Thus 1e, 1f, 1g and 1h showed activity against Erysiphe (barley), 2a against Puccinia (wheat) and 6a against Botrytis (apple).Of particular interest is the high gameticidal activity of 3a in the greenhouse.