80249-08-7

Upstream product

• 31842-97-4 2(R)-hydroxymethyl-1,2,3,4,6,7,12,12b-octahydroindolo<2,3-a>quinolizine 
• 31842-99-6 2(R)-acetoxymethyl-1,2,3,4,6,7,12,12b-octahydroindolo<2,3-a>quinolizine 
• 79228-00-5 4-oxo-3,4,6,7,12,12b-hexahydro-1H-indolo[2,3-a]quinolizine-2,2-dicarboxylic acid diethyl ester 
• 80249-01-0 2(S)-ethoxycarbonyl-4-oxo-1,2,3,4,6,7,12,12b(S)-octahydroindolo<2,3-a>quinolizine 
• 80249-01-0 2(S)-ethoxycarbonyl-4-oxo-1,2,3,4,6,7,12,12b-octahydroindolo<2,3-a>quinolizine 
• 31842-99-6 2(R)-acetoxymethyl-1,2,3,4,6,7,12,12b(R)-octahydroindolo<2,3-a>quinolizine 
• 80249-03-2 2(S)-hydroxymethyl-4-oxo-1,2,3,4,6,7,12,12b(R)-octahydroindolo<2,3-a>quinolizine 
• 501-53-1 benzyl chloroformate 
• 67-56-1 methanol 
• 31842-97-4 2(R)-hydroxymethyl-1,2,3,4,6,7,12,12b(R)-octahydroindolo<2,3-a>quinolizine 
• 31842-99-6 2(R)-acetoxymethyl-1,2,3,4,6,7,12,12b(S)-octahydroindolo<2,3-a>quinolizine 
• 80249-03-2 2(S)-hydroxymethyl-4-oxo-1,2,3,4,6,7,12,12b(S)-octahydroindolo<2,3-a>quinolizine 
• 31842-97-4 2(R)-hydroxymethyl-1,2,3,4,6,7,12,12b(S)-octahydroindolo<2,3-a>quinolizine 

Downstream Products

• 80249-10-1 3-benzyloxycarbonyl-6(R),9-methano-8(S)-methoxy-1,2,3,4,5,6,7,8-octahydro-9H-azecino<5,4-b>indole 
• 80249-09-8 3-benzyloxycarbonyl-6(R)-methanesulphonyloxymethyl-8(S)-methoxy-1,2,3,4,5,6,7,8-octahydro-9H-azecino<5,4-b>indole 
• 80249-10-1 3-benzyloxycarbonyl-6(R),9-methano-8(R)-methoxy-1,2,3,4,5,6,7,8-octahydro-9H-azecino<5,4-b>indole 
• 80249-09-8 3-benzyloxycarbonyl-6(R)-methanesulphonyloxymethyl-8(R)-methoxy-1,2,3,4,5,6,7,8-octahydro-9H-azecino<5,4-b>indole 

Relevant academic research and scientific papers

ON THE STEREOCHEMISTRY OF THE SOLVOLYTIC C/D RING CLEAVAGE OF THE 1,2,3,4,6,7,12,12b-OCTAHYDROINDOLOQUINOLIZINE SYSTEM

A model sequence for the synthesis of C-mavacurine-type alkaloids is elaborated to demonstrate that substitution at C-12b in the reactions of the amines (4) with cyanogen bromide and methanol (Scheme 6) proceeds with stereospecific inversion of configurat