80255-17-0Relevant articles and documents
Preparation of Polyfunctional Nitro Olefins and Nitroalkanes Using the Copper-Zinc Reagents RCu(CN)ZnI
Jubert, Carole,Knochel, Paul
, p. 5431 - 5438 (2007/10/02)
The addition of the copper-zinc reagents RCu(CN)ZnX to a variety of nitro olefins produces polyfunctional nitroalkanes in high yields.The intermediate zinc or copper nitronates can be directly submitted to a Nef reaction (O3, -78 deg C) and converted to p
32. 2'-Nitro-2'-propen-1'-yl 2,2-Dimethylpropanoate (NPP), A Multiple Coupling Reagent
Seebach, Dieter,Knocherl, Paul
, p. 261 - 283 (2007/10/02)
The title compound 1 (NPP) is prepared from formaldehyde, nitromethane, and pivaloyl chloride.It is shown to be a versatile nitroallylating reagent combining with nucleophiles as different as anilines, indoles, enolates, and organolithium compounds.This i