802622-21-5

Basic information

• Product Name: 3-[(1R,2R)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one
• Synonyms: 3-[(1R,2R)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one
• CAS NO: 802622-21-5
• Molecular Weight: 650.103
• Mol File: 802622-21-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[(1R,2R)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[(1R,2R)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one(802622-21-5)
• EPA Substance Registry System: 3-[(1R,2R)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one(802622-21-5)

Safety Data

• Hazardous Substances Data: 802622-21-5(Hazardous Substances Data)

Upstream product

• 2043-21-2 acryloyl-1,3-oxazolidin-2-one 
• 802622-04-4 3Z-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene 
• 802622-00-0 3Z-4,8-dimethyl-3-(triisopropylsiloxymethyl)-3,7-nonadien-2-ol 
• 802622-02-2 3Z-4,8-dimethyl-3-(triisopropylsiloxymethyl)-3,7-nonadien-2-one 
• 54345-41-4 7-methyl-6-octen-2-ynoic acid ethyl ester 
• 22842-10-0 2-methylhept-2-en-6-yne 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Relevant articles and documents

Challenge toward structural complexity using asymmetric catalysis: Target-oriented development of catalytic enantioselective Diels-Alder reaction

(Chemical Equation Presented) A new method for the catalytic enantioselective Diels-Alder reaction using polysubstituted silyl enol ethers as dienes is described. High enantioselectivity (up to 92% ee) was produced using a catalyst generated from FeBr3 and AgSbF6 in a 1:2 ratio and aryl-pybox (aryl = Ph or p-ethoxyphenyl). This reaction should facilitate the enantioselective synthesis of polycyclic acylphloroglucinols such as hyperforin or garsubellin A, which are currently of interest from synthetic and medicinal points of view.