80263-47-4

Upstream product

• 18100-80-6 2,3,5-triphenyl-4-thiazolone 
• 4410-33-7 N-phenyl-2-hydroxy-4-phenylacetamide 

Downstream Products

• 93-98-1 N-phenyl benzoyl amide 
• 4732-66-5 2-oxo-N,2-diphenylacetamide 
• 80263-48-5 2,3,5-triphenyl-1,3-oxazolium-4-olate 
• 130520-10-4 1,2,4-triphenyl-1,2-dihydro-1,4-epoxy-4a,8a-methanoisoquinolin-3(4H)-one 
• 80263-49-6 (2S,6R)-1,4,7,8-Tetraphenyl-10-oxa-4,8-diaza-tricyclo[5.2.1.0^2,6]decane-3,5,9-trione 
• 24334-54-1 2-oxo-1-phenyl-2-(phenylamino)ethyl benzoate 
• 80300-25-0 C₃₁H₂₂N₂O₄ 

Relevant academic research and scientific papers

Novel Synthesis of the Mesoionic System 1,3-Oxazolium-4-olate

Thermolysis or photolysis of N-phenyldibenzoylnitrone (1) produces N-benzoylphenylglyoxanilide (5) and not the previously reported oxaziridine 2.Treatment of imide 5 with triethyl phosphite produced 2,3,5-triphenyl-1,3-oxazolium-4-olate (8), a new member

Heterocycles by Cycloaddition. Part 9. Bridged Heteroannulenes by Cycloaddition-Extrusion-Ring-expansion Reactions of Mesoionic Compounds with Benzocyclopropene. A Methanothiazonine, a Methanothionine, and a Methanothiecinone

A methanothiazonine (13) was formed by cycloaddition-extrusion-ring expansion of benzocyclopropene with a mesoionic oxathiazoliumolate (12).The reaction with a dithioliumolate (14) gave the cycloadduct (15), from which a methanothionine (16) and a methano

PHOTOCHEMICAL AND THERMAL REACTIONS OF HETEROCYCLES. IV. PHOTO-OXIDATION REACTIONS OF MESOIONIC DITHIOLIUMOLATE, THIAZOLIUMOLATE, AND RELATED HETEROCYCLES. SOLVENT EFFECTS ON THE COURSE OF THE PHOTO-OXIDATION

Photo-oxidation of mesoionic 1,3-dithiolium-4-olates (1) gave diacyl disulfide (2), and that of a mesoionic thiazolium-4-olate (6) and oxazolium-5-olate (9) gave diacylamides as the main products.The formation of these products was rationalized by a route involving fragmentation of the corresponding endoperoxides, which are formed by cycloaddition of singlet oxygen on the mesoionic rings.Photo-oxidation of 5(4H)-oxazolones (12) and a 5(4H)-thiazolone (17) in dichloromethane gave the corresponding dehydro-dimers, while that of the former in dimethylformamide gave mainly diacylamides.The acylamides were considered to arise via the endoperoxides of the mesoionic tautomers.