80352-67-6

Upstream product

• 763-32-6 2-methyl-1-buten-4-ol 
• 781-03-3 isopentenyl tosylate 
• 80352-66-5 4-mesyloxy-2-methylbutene 
• 72445-18-2 (3-methylbut-3-en-1-yl)(phenyl)sulfane 
• 108-98-5 thiophenol 

Downstream Products

• 83180-97-6 2-Methyl-2-(3-methyl-1-phenylsulfanyl-but-3-enyl)-cyclopentanone 
• 83181-07-1 1-(3-Methyl-1-phenylsulfanyl-but-3-enyl)-cyclohexanecarboxylic acid methyl ester 
• 83180-99-8 2,2,5-Trimethyl-1-phenyl-3-phenylsulfanyl-hex-5-en-1-one 
• 83181-13-9 2,2,7-Trimethyl-5-phenylsulfanyl-oct-7-en-3-one 
• 16627-79-5 (E) 3-methyl-1,3-butadienyl phenyl sulfide 
• 66463-96-5 (E)-3-methyl-1-(phenylsulfinyl)buta-1,3-diene 
• 35346-80-6 sulfure de (methyl-3 buten-3 yn-1) yle et de phenyle 
• 83180-95-4 2-Methyl-2-(3-methyl-1-phenylsulfanyl-but-3-enyl)-cyclohexanone 
• 65597-73-1 1,1-(bisphenylthio)-3-methyl-3-butene 
• 83181-12-8 2-(3-Methyl-1-phenylsulfanyl-but-3-enyl)-cyclopentanone 
• 83181-09-3 2,5-Dimethyl-3-phenylsulfanyl-hex-5-enoic acid methyl ester 
• 83181-01-5 4,7-Dimethyl-5-phenylsulfanyl-oct-7-en-3-one 
• 83181-11-7 2-Ethyl-5-methyl-3-phenylsulfanyl-hex-5-enoic acid ethyl ester 
• 83181-03-7 2,5-Dimethyl-1-phenyl-3-phenylsulfanyl-hex-5-en-1-one 

Relevant academic research and scientific papers

O-SILYLATED ENOLATE PHENYLTHIOALKYLATION: A NEW SYNTHESIS OF UNSATURATED 1,5-DICARBONYL COMPOUNDS.

The O-silylated enolates of ketones and esters can be phenylthioalkylated by the chlorides (2) and (3) under ZnBr2-catalysis; ozonolysis and subsequent sulphoxide thermolysis then gives the corresponding unsaturated 1,5-dicarbonyl compounds.