781-03-3

Basic information

• Product Name: 1-methyl-4-(3-methylbut-3-enoxysulfonyl)benzene
• Synonyms: 1-methyl-4-(3-methylbut-3-enoxysulfonyl)benzene
• CAS NO: 781-03-3
• Molecular Formula: C₁₂H₁₆O₃S
• Molecular Weight: 0
• Mol File: 781-03-3.mol
• Article Data: 41

Chemical Properties

• Boiling Point: 350.2°C at 760 mmHg
• Flash Point: 165.6°C
• Appearance: /
• Density: 1.118g/cm³
• Vapor Pressure: 9.03E-05mmHg at 25°C
• Refractive Index: 1.513
• CAS DataBase Reference: 1-methyl-4-(3-methylbut-3-enoxysulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-4-(3-methylbut-3-enoxysulfonyl)benzene(781-03-3)
• EPA Substance Registry System: 1-methyl-4-(3-methylbut-3-enoxysulfonyl)benzene(781-03-3)

Safety Data

• Hazardous Substances Data: 781-03-3(Hazardous Substances Data)

Usage

Uses

Isopentenyl Tosylate is an intermediate in the synthesis of Isopentenyl Pyrophosphate Triammonium Salt (I821850) which is used for the preparation of antitumor agents phosphohalohydrins.

InChI:InChI=1/C12H16O3S/c1-10(2)8-9-15-16(13,14)12-6-4-11(3)5-7-12/h4-7H,1,8-9H2,2-3H3

Upstream product

• 25859-52-3 methyl 3-methyl-3-butenoate 
• 74915-94-9 1-(tert-butyldimethylsiloxy)-3-methyl-3-butene 
• 763-32-6 2-methyl-1-buten-4-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 295785-51-2 1-(Bis-phenylsulfanyl-methyl)-2-(3-methyl-but-3-enyloxy)-benzene 
• 336106-26-4 1-(3-methylbut-3-en-1-yl)-1H-benzo[d]imidazole 
• 2080-62-8 4-methyl-N-(3-methylbut-3-en-1-yl)benzenesulfonamide 
• 654065-79-9 N,N-bis(3-methyl-3-butenyl)-p-toluenesulfonamide 
• 169330-64-7 1-iodo-2-((3-methylbut-3-en-1-yl)oxy)benzene 
• 752207-04-8 methyl 2,2-diphenyl-5-methyl-5-hexenoate 
• 654065-73-3 N-(3-butenyl)-N-(3-methyl-3-butenyl)-p-toluenesulfonamide 
• 80352-67-6 1-chloro-3-methylbut-3-en-1-yl phenyl sulfide 
• 83181-01-5 4,7-Dimethyl-5-phenylsulfanyl-oct-7-en-3-one 
• 83180-97-6 2-Methyl-2-(3-methyl-1-phenylsulfanyl-but-3-enyl)-cyclopentanone 
• 83180-95-4 2-Methyl-2-(3-methyl-1-phenylsulfanyl-but-3-enyl)-cyclohexanone 
• 116057-53-5 isopentenyl pyrophosphate ammonium salt 
• 1065474-56-7 2-[benzyl(3-methylbut-3-en-1-yl)amino]benzonitrile 
• 71434-19-0 (+/-)-5-methyl-1-phenylhex-5-en-1-ol 

Relevant articles and documents

Properties of plasmodium falciparum with a deleted apicoplast DNA gyrase

Malaria parasites have three genomes: a nuclear genome, a mitochondrial genome, and an apicoplast genome. Since the apicoplast is a plastid organelle of prokaryotic origin and has no counterpart in the human host, it can be a source of novel targets for a

Ruthenium Metathesis: A Key Step to Access a New Cyclic Tetrasubstituted Olefin Platform

An rapid and mild synthetic route for the preparation of cyclic tetrasubstituted platforms via ruthenium-catalyzed ring-closing metathesis (RCM) has been developed. This process tolerates a wide range of functionalities such as nitrogen, oxygen, sulfur, silicon, and carbon tethered groups, as well as very challenging fluorine and boron atoms (36 derivatives, up to 96%). This diversity-oriented method was further demonstrated by the postfunctionalization reactions, such as Pd-couplings, N-substitution, and reductive amination introducing a morpholine moiety.

Pd-catalyzed regiodivergent synthesis of diverse oxindoles enabled by the versatile heck reaction of carbamoyl chlorides

We report herein a miscellaneous oxindole synthesis bearing an all-carbon quaternary center, enabled by Pd-catalyzed intramolecular cyclization followed by multiple intermolecular Heck reactions of both easily accessible alkene-tethered carbamoyl chlorides and olefins. This protocol obviates the use of prefunctionalized olefinic reagents, exhibits excellent functional group tolerance, and features fascinating reactive versatility.