80376-45-0Relevant articles and documents
Sequential Ene Reactions. A New Annelation Procedure
Snider, Barry B.,Deutsch, Ethan A.
, p. 745 - 747 (1982)
Alkylidenecycloalkanes react with α,β-unsaturated carbonyl compounds in the presence of Me2AlCl to give bicyclic alcohols resulting from two sequential ene reactions.
Sequential Ene Reactions. A New Annelation Procedure
Snider, Barry B.,Deutsch, Ethan A.
, p. 1822 - 1829 (2007/10/02)
Alkylidenecycloalkanes 1 undergo two sequential Me2AlCl-catalyzed ene reactions with α,β-unsaturated carbonyl compounds to give bicyclic alcohols 3.At low temperatures, the initial ene adducts 2 can be isolated when vinyl ketones are used.This reaction ha