80389-23-7Relevant articles and documents
Regioselectivity control in a Diels-Alder reaction of a surfactant 1,3- diene with a surfactant dienophile
Jaeger, David A.,Su, Dan
, p. 257 - 260 (1999)
The Diels-Alder reaction of surfactant 1,3-diene 1 and surfactant dienophile 2 within aqueous mixed micelles at 25°C gave a 6.6:1 ratio of cycloadducts 11 and 12, and that of nonsurfactant analogues 10 and 13 in C6H5Me at 75(85) °C gave a 1:l ratio of cycloadducts 14 and 15. The regioselectivity of the reaction of 1 and 2 was controlled by their alignment at the mixed micelle-H2O interface.