Tetrahedron Letters p. 257 - 260 (1999)
Update date:2022-08-04
Topics:
Jaeger, David A.
Su, Dan
The Diels-Alder reaction of surfactant 1,3-diene 1 and surfactant dienophile 2 within aqueous mixed micelles at 25°C gave a 6.6:1 ratio of cycloadducts 11 and 12, and that of nonsurfactant analogues 10 and 13 in C6H5Me at 75(85) °C gave a 1:l ratio of cycloadducts 14 and 15. The regioselectivity of the reaction of 1 and 2 was controlled by their alignment at the mixed micelle-H2O interface.
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