80389-88-4

Basic information

• Product Name: fac-(CO)3Mn(Cl)S₂CCMe₂PPh₃
• CAS NO: 80389-88-4
• Molecular Weight: 554.937
• Mol File: 80389-88-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: fac-(CO)3Mn(Cl)S₂CCMe₂PPh₃(CAS DataBase Reference)
• NIST Chemistry Reference: fac-(CO)3Mn(Cl)S₂CCMe₂PPh₃(80389-88-4)
• EPA Substance Registry System: fac-(CO)3Mn(Cl)S₂CCMe₂PPh₃(80389-88-4)

Safety Data

• Hazardous Substances Data: 80389-88-4(Hazardous Substances Data)

Upstream product

• 14100-30-2 pentacarbonylchloromanganese(I) 
• 69491-12-9 2-methyl-2-(triphenylphosphonio)dithiopropionate betaine 

Relevant articles and documents

KOORDINATIONSCHEMIE FUNKTIONELLER PHOSPHORYLIDE. III. NEUE MANGAN- UND RHENIUM-KOMPLEXE MIT TRIPHENYLPHOSPHONIO-ALKANDITHIOCARBOXYLAT-LIGANDEN

As strong nucleophiles, phosphorus ylids easily attack heteroallenes.The addition of isopropylidene triphenylphosphorane to carbon disulfide yields the zwitterionic adduct Ph3CMe2CS2-, which reacts to bis(isopropylidene)-1,2,4-trithiolane by thermal or, coordinated to transition metals, photochemical activation according to a cycloaddition mechanism.By reaction of the betaine with manganese and rhenium carbonyl halides under exclusion of light, stable monomeric and dimeric fac-tricarbonyl complexes with the composition (CO)3(X)S2CCMe2Ph3 (M=Mn, Re; X=Cl, Br) are obtained which are distinguished by their spectra (IR, NMR, UV).The monomeric bromomanganese and -rhenium complexes are isomorphous and crystallize in the space group P21/c (monoclinic, Z=4).