80426-23-9

Basic information

• Product Name: Lithium, [2,6-bis(trifluoromethyl)phenyl]-
• CAS NO: 80426-23-9
• Molecular Formula: C8H3F6Li
• Molecular Weight: 220.043
• Mol File: 80426-23-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Lithium, [2,6-bis(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, [2,6-bis(trifluoromethyl)phenyl]-(80426-23-9)
• EPA Substance Registry System: Lithium, [2,6-bis(trifluoromethyl)phenyl]-(80426-23-9)

Safety Data

• Hazardous Substances Data: 80426-23-9(Hazardous Substances Data)

Upstream product

• 402-31-3 1,3-bis(trifluoromethyl)benzene 

Downstream Products

• 841255-69-4 (2,6-(CF₃)2C₅H₃)SbCl₂ 
• 841255-70-7 (2,4-(CF₃)2C₅H₃)SbCl₂ 
• 841255-71-8 (2,6-(CF₃)2C₅H₃)2SbCl 
• 841255-72-9 (2,4-(CF₃)2C₅H₃)2SbCl 
• 841255-73-0 (2,6-(CF₃)2C₆H₃)(2,4-(CF₃)2C₅H₃)2Sb 
• 508194-39-6 chlorobis[2,6-bis(trifluoromethyl)phenyl]germane 
• 650583-83-8 bis[2,4-bis(trifluoromethyl)phenyl]dichlorogermane 
• 650583-84-9 bis[2,4-bis(trifluoromethyl)phenyl]dichlorostannane 
• 650583-85-0 bis[2,6-bis(trifluoromethyl)phenyl]dichlorostannane 
• 681812-10-2 (2,4-(CF₃)2C₆H₃)2BF*OEt₂ 
• 681812-04-4 2,6-(CF₃)2C₆H₃BCl₂ 
• 681812-05-5 bis(2,6-bis(trifluoromethyl)phenyl)fluoroborane 

Relevant articles and documents

Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)3C6 H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′), or 2,4-(CF3)2 C6H3 (Ar″) ligands

Several new boron compounds containing the 2,4,6- (CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised from reactions of ArLi, Ar′Li or Ar″Li with BCl3, and characterised by 19F and 11B NMR spectroscopy. Chlorine/fluorine exchanges are evident in these reactions. The crystal and molecular structures of Ar2BF, Ar″3B, Ar2B(OH), Ar′B(OH)2 and Mes2BF (Mes = 2,4,6-Me3C6H2) have been determined by single crystal X-ray diffraction. Ar″3B represents the first example of a compound containing three Ar″ ligands to be structurally characterised. Molecular geometries and GIAO-NMR shifts for several new boron compounds have been calculated at the HF/6-31G* level of theory, and compared with the available experimental results.