80446-29-3

Upstream product

• 42846-36-6 trans-4,5-dibromo-1-cyclohexene 
• 1165952-92-0 cyclohexa-1,4-diene 
• 62199-53-5 4,5-dibromocyclohexene 

Downstream Products

• 51622-32-3 rac-3,4-Dibrom-adipinsaeure 
• 104286-32-0 C₁₉H₁₈O₂ 
• 104286-31-9 C₁₉H₁₈O₂ 
• 104286-28-4 2-Methoxy-3a,7a-dihydro-benzo[1,3]dioxole 
• 80409-76-3 C₂₇H₂₂O₂ 
• 80409-79-6 C₂₇H₂₂O₂ 
• 80409-74-1 (2α,3aα,7aα)-3a,7a-dihydro-2-phenyl-1,3-benzodioxole 
• 104286-32-0 C₁₉H₁₈O₂ 
• 104286-31-9 C₁₉H₁₈O₂ 
• 80409-80-9 (2α,3aβ,5β,6α,7aβ)-5,6-dibromohexahydro-2-phenyl-1,3-benzodioxole 

Relevant academic research and scientific papers

Base-Mediated Fragmentation of Bicyclic Dihydro-3,6-oxazines: Transformation of Nitroso Diels-Alder Cycloadducts

Nitroso Diels-Alder cycloadditions of benzene oxide with various acyl-nitroso derivatives are described. Treatment of these cycloadducts with methyllithium results in a fast fragmentation reaction, leading to highly functionalized cyclic amino alcohols. T

An efficient and highly stereoselective synthesis of gala-Quercitol from 1,4-cyclohexadiene

gala-Quercitol was synthesized from 1,4-cyclohexadiene in seven steps and overall yield of 68%. Reaction of 5,6-dibromo-2,2-dimethylhexahydro-1,3-benzodioxole, synthesized from 1,4-cyclohexadiene in three steps, with excess NaOMe gave (3aα,5α,7aα)-5-metho

Chemistry of Benzene-Anthracene Cyclodimers

Synthesis of the formal s + 4?s> and s + 2?s> adducts of benzene and anthracene (1 and 2) has made possible the observation of features on the potential-energy surfaces that govern Woodward-Hoffmann-allowed and -forbidden cycloreversions.The thermal dissociation of 1 is not chemiluminescent in spite of favorable kinetic and thermodynamic parameters, and its photochemical dissociation yields excited anthracene in very high efficiency (ΦAn* = 0.80).The enthropy of activation in the thermal dissociation of 2 is negative, and the photochemical dissociation of 2 yields excited anthracene in low but appreciable efficiency (ΦAn* = 0.08).Comparision of these data clearly demonstrates orbital symmetry control of both the ground- and excited-state reactions.