804519-82-2

Basic information

• Product Name: 3-Pentanone, 1-cyclohexyl-1-hydroxy-2-methyl-, (1S,2S)-
• CAS NO: 804519-82-2
• Molecular Formula: C12H22O2
• Molecular Weight: 198.305
• Mol File: 804519-82-2.mol

Chemical Properties

• CAS DataBase Reference: 3-Pentanone, 1-cyclohexyl-1-hydroxy-2-methyl-, (1S,2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone, 1-cyclohexyl-1-hydroxy-2-methyl-, (1S,2S)-(804519-82-2)
• EPA Substance Registry System: 3-Pentanone, 1-cyclohexyl-1-hydroxy-2-methyl-, (1S,2S)-(804519-82-2)

Safety Data

• Hazardous Substances Data: 804519-82-2(Hazardous Substances Data)

Upstream product

• 1072-72-6 Tetrahydrothiopyran-4-one 
• 2043-61-0 cyclohexanecarbaldehyde 
• 804519-66-2 (S)-3-((S)-Cyclohexyl-hydroxy-methyl)-tetrahydro-thiopyran-4-one 
• 100420-03-9 (4S,5R)-2,2-diethyl-4-methyl-5-phenyl-1,3-oxazolidine 

Relevant articles and documents

Proline-catalyzed asymmetric aldol reactions of tetrahydro-4H-thiopyran-4- one with aldehydes

Proline-catalyzed enantioselective direct intermolecular aldol reactions of tetrahydro-4H-thiopyran-4-one with various aldehydes give anti adducts with high diastereo- and enantioselectivities in moderate to excellent yields. With the aromatic aldehydes b

HIGHLY ENANTIOSELECTIVE SYNTHESIS OF ANTI(THREO)-ALDOLS BY THE ASYMMETRIC ALDOL REACTION UTILIZING A CHIRAL AZAENOLATE

Diastereo- and enantioselective aldol reaction between 3-pentanone and aldehydes is achieved utilizing a chiral oxazolidine derived from 3-pentanone and chiral norephedrine.The reaction of a tin(II) azaenolate generated from the chiral oxazolidine with aldehydes affords predominantly anti(threo)-aldols of high enantiomeric purity.