804530-36-7Relevant articles and documents
Sequential coupling of zincated hydrazone, alkenylboronate, and electrophile that creates several contiguous stereogenic centers
Nakamura, Masaharu,Hatakeyama, Takuji,Hara, Kenji,Fukudome, Hiroki,Nakamura, Eiichi
, p. 14344 - 14345 (2004)
A zincated N,N-dimethylhydrazone of a ketone undergoes stereospecific syn addition to E- or Z-alkenylboronate to generate a γ-Zn/B dimetallic intermediate, which reacts with a carbon electrophile to give a γ-borylhydrazone in good yield with excellent dia